The existence of a symmetrically bridged, ferromagnetically coupled Cu2Cl62– dimer in (Ph4As)CuCl3, with bridging Cu–Cl–Cu angles of 93·6°, ca. 2° smaller than for antiferromagnetically coupled dimers, has been confirmed by an X-ray crystal structure determination.
R. D. Willett, J. Chem. Soc., Chem. Commun., 1973, 607 DOI: 10.1039/C39730000607
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