Bidentate di-N- or di-P-donors are internally metallaed by platinum or palladium very much less readily than analogous monodentate ligands but metallation can be promoted by increasing the chelate ring size from five to six and by using certain reagents.
M. G. Clerici, B. L. Shaw and B. Weeks, J. Chem. Soc., Chem. Commun., 1973, 516 DOI: 10.1039/C39730000516
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