When Me3Si–Co(CO)4 is heated at 105° for 50 h, migration of the Me3Si group from cobalt to oxygen takes place to give Me3SiOCCo3(CO)9 and (Me3SiOC)4Co2(CO)4; the former compound is also formed in high yields within an hour at room temperature by the reaction of Me3SiCo(CO)4 with tetrahydrofuran.
W. M. Ingle, G. Preti and A. G. MacDiarmid, J. Chem. Soc., Chem. Commun., 1973, 497 DOI: 10.1039/C39730000497
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