The abstraction of a diastereotopic hydrogen (1,4) in the silver oxide–bromine catalysed formation of tetrahydrofurans from three acyclic secondary alcohols has been shown to be stereoanalogous to the hydrogen abstraction in lead tetra-acetate generated alkoxy-radicals in the same molecules.
M. M. Green, J. M. Moldowan and J. G. McGrew, J. Chem. Soc., Chem. Commun., 1973, 451 DOI: 10.1039/C39730000451
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