A cell-free system from Andrographis paniculata tissue cultures incorporates 3H from (3RS)-[2-14C, 5-3H2]mevalonate into trans,trans-farnesol without loss and into the cis,trans-isomer with loss of one sixth of the label; this strongly supports trans→cisisomerisation via aldehydes.
K. H. Overton and F. M. Roberts, J. Chem. Soc., Chem. Commun., 1973, 378 DOI: 10.1039/C39730000378
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