The reaction of cyclopentadiene with Ru3(CO)12 yields Ru(π-C5H5)(CO)2(H) quantitatively, via intermediate formation of Ru(2–5-η-cyclopentadiene)(CO)3; hydrides M(π-C5H5)(CO)2(H)(M = Ru, Os) are similarly formed from H4Ru4(CO)12 and H2Os3(CO)10.
A. P. Humphries and S. A. R. Knox, J. Chem. Soc., Chem. Commun., 1973, 326 DOI: 10.1039/C39730000326
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