Kinetic studies of the reaction between carbon monoxide and (piperidine)2Fe(porphyrin) complexes to give (piperidine)Fe(CO)(porphyrin) show that the mechanism involves predissociation to a five-co-ordinate (piperidine)Fe(porphyrin) complex; the data for the protoporphyrin IX system suggest that the model may resemble closely in kinetic properties the active iron site in deoxy-myoglobin and -hemoglobin.
D. V. Stynes and B. R. James, J. Chem. Soc., Chem. Commun., 1973, 325 DOI: 10.1039/C39730000325
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