Biogenetically modelled synthesis of a samandarine-type alkaloid
Abstract
The 3-aza-4-oxo-lactam produced by Schmidt rearrangement of 17β-acetoxy-1α-hydroxy-5β-androstan-3-one was reduced to yield a samandarine-type salamander alkaloid.
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J. Chem. Soc., Chem. Commun., 1973, 288-289
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Biogenetically modelled synthesis of a samandarine-type alkaloid
M. H. Benn and R. Shaw, J. Chem. Soc., Chem. Commun., 1973, 288 DOI: 10.1039/C39730000288
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