Two mechanisms, radical formation and isomerization, have been identified for the thermal decomposition of unsymmetric cis-azo-compounds; the photochemical behaviour of trans-azo-compounds is dependent on the thermal behaviour of the corresponding cis-azo-isomer.
N. A. Porter and M. O. Funk, J. Chem. Soc., Chem. Commun., 1973, 263 DOI: 10.1039/C39730000263
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