The 29Si–{1H} nuclear Overhauser effect is found to be substantial for Ph3SiH but small for PhSiH3; the difference in behaviour is attributed to the low barrier to internal rotation about the Si–C bond in phenylsilane itself.
R. K. Harris and B. J. Kimber, J. Chem. Soc., Chem. Commun., 1973, 255 DOI: 10.1039/C39730000255
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