The photolysis of 2-(oxiranyl)cycloalkanones is shown to be a useful method for the synthesis of unsaturated macrolides by a three-atom photochemical ring expansion.
R. G. Carlson, J. H. Huber and D. E. Henton, J. Chem. Soc., Chem. Commun., 1973, 223 DOI: 10.1039/C39730000223
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