Issue 5, 1973

Reaction of 1,2-benzocyclobutadienequinone with zerovalent platinum: preparation and structure of (1,1-bistriphenylphosphine)platinabenzocyclopentenedione

Abstract

The reaction of tetrakis(triphenylphosphine)platinum with 1,2-benzocyclobutadienequinone (1) effects an unsymmetrical opening of, and insertion of Pt(PPh3)2 into, the four-membered ring of (1) to give two conformers of the title compound, whose crystal structures have been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 158-159

Reaction of 1,2-benzocyclobutadienequinone with zerovalent platinum: preparation and structure of (1,1-bistriphenylphosphine)platinabenzocyclopentenedione

J. A. Evans, G. F. Everitt, R. D. W. Kemmitt and D. R. Russell, J. Chem. Soc., Chem. Commun., 1973, 158 DOI: 10.1039/C39730000158

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements