Activated aromatic compounds react with phthalimidonitrene (1) generated from the aziridine (2), to give mostly 3H-azepines (3), but with the nitrene from lead tetra-acetate oxidation of N-aminophthalimide to give mostly the insertion products (5).
D. W. Jones, J. Chem. Soc., Chem. Commun., 1973, 67 DOI: 10.1039/C39730000067
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