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Issue 0, 1973
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Thermodynamic studies of fluoroalcohols. Part 3.—The thermodynamics of transfer of five fluoroalcohols from the gas-phase to aqueous solution

Abstract

The free energies, enthalpies, entropies, and heat capacities of transfer of five fluoroalcohols from the gas-phase to aqueous solution at infinite dilution and at four temperatures have been determined. The results are primarily discussed in terms of the solute–solvent interactions between fluorinated alkyl-groups and water molecules in aqueous solution. Fluorocarbon groups promote in adjacent water molecules a structure which may possibly be ice-like in character.

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Article information


J. Chem. Soc., Faraday Trans. 1, 1973,69, 1577-1585
Article type
Paper

Thermodynamic studies of fluoroalcohols. Part 3.—The thermodynamics of transfer of five fluoroalcohols from the gas-phase to aqueous solution

C. H. Rochester and J. R. Symonds, J. Chem. Soc., Faraday Trans. 1, 1973, 69, 1577
DOI: 10.1039/F19736901577

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