From coupling-constant data for a series of 2-substituted 1,2-dihydronaphthalenes it is concluded that 2-carboxy, 2-methoxycarbonyl, and 2-ethoxycarbonyl substituents preferentially occupy the pseudo-equatorial position whereas a 2-chlorocarbonyl group shows no conformational preference. The pseudo-axial preferences found here and elsewhere for substituents in the 1-position are discussed in terms of peri H interactions.
M. J. Cook and N. L. Dassanayake, J. Chem. Soc., Perkin Trans. 2, 1972, 1901 DOI: 10.1039/P29720001901
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...