Helicobasidin has been shown to incorporate four tritium atoms from [2,2-3H2]mevalonate, two from 4R-[4-3H]-mevalonate, and two from [5,5-3H2]mevalonate. Feeding with [2-3H,2-14C]geranyl pyrophosphate has shown that the 4R-mevalonoid tritium atom from the second prenyl unit is retained in the biosynthesis.
P. M. Adams and J. R. Hanson, J. Chem. Soc., Perkin Trans. 1, 1972, 586 DOI: 10.1039/P19720000586
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