Dialkyl oxalates decomposed in the presence of iodine at temperatures at which the pure diesters were stable. Dioctadecanyl, dicyclohexyl, and di-1-adamantyl oxalate gave the corresponding iodides, whereas dibenzyl oxalate gave diphenylmethane. The mechanism of the iodine-induced decomposition of dialkyl oxalates is discussed.
A. Goosen and A. Scheffer, J. Chem. Soc., Perkin Trans. 1, 1972, 369 DOI: 10.1039/P19720000369
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