Issue 0, 1972

One-step synthesis of cis-5,6-dideuterio-cis-cyclo-octene and its thermal stability towards concerted, intramolecular transfer of hydrogen

Abstract

cis-5,6-Dideuterio-cis-cyclo-octene has been synthesised in one step from cyclo-octa-1,5-diene by reduction with dideuteriodi-imide. On prolonged pyrolysis at 250°, intramolecular transfer of the vicinal 5- and 6-protons to the double bond does not occur; thus no 1,2-dideuterio-cis-cyclo-octene is formed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 342-344

One-step synthesis of cis-5,6-dideuterio-cis-cyclo-octene and its thermal stability towards concerted, intramolecular transfer of hydrogen

A. J. Bellamy, J. Chem. Soc., Perkin Trans. 1, 1972, 342 DOI: 10.1039/P19720000342

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