Pyrolysis at 180–200° of N-aryldithiocarbamates, prepared from arylamines, affords isothiocyanates in high yield. In contrast to other isothiocyanate syntheses, this method does not require basic conditions or a strongly electron-withdrawing group on the thiol sulphur atom.
R. M. Ottenbrite, J. Chem. Soc., Perkin Trans. 1, 1972, 88 DOI: 10.1039/P19720000088
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