The 2Eg→4A2g phosphorescence of a series of carefully purified salts containing the Cr(NH3)3+6 ion has been measured from 300 to 4 K. All seven τ1u and two of the τ2u fundamentals act as vibronic origins and the first members of progressions in the εg modes are observed. This is evidence for a Jahn-Teller effect in the 4T2g state.
C. D. Flint and P. Greenough, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 897 DOI: 10.1039/F29726800897
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