Photoelectron spectra of (MH3)2Y and MH3SH (M = C,Si,Ge; Y = O,S,Se,Te) have been observed and the bands assigned to the expected valence-shell energy levels. The results are consistent with the existence of (p→d)π-bonding for all the compounds with M = Si,Ge.
S. Cradock and R. A. Whiteford, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 281 DOI: 10.1039/F29726800281
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