νmax and εmax for the n–π* transition of acetone in aqueous solution do not vary monotonically with acetone concentration. The Klotz-Worley R parameter for these solutions shows a maximum at 0.05 x2 whereas carbonyl infrared intensities are a linear function of acetone concentration. Hydrophobic hydration of acetone is proposed in the initial region with direct molecular interaction at approximately 0.20 and 0.45 x2.
M. F. Fox, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 1294 DOI: 10.1039/F19726801294
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