Wolkenstein's bond polarizability approach to Raman intensities is applied to the terminal carbonyls stretching vibrations of some metal carbonyl species. General intensity formulae are given and the cases of M(CO)6(M = Cr, Mo, and W); RM (CO)3[RM =(π-C5H5)Mn or (arene)Cr, arene = simple or substituted benzene rings]; RM(CO)5(RM = BrMn and Ph3SnRe) are discussed in detail.
S. F. A. Kettle, I. Paul and P. J. Stamper, J. Chem. Soc., Dalton Trans., 1972, 2413 DOI: 10.1039/DT9720002413
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