The reaction of tantalum tetrachloride with acetonitrile yields the diamagnetic dimer [TaCl3(MeCN)2]2. From these acetonitrile solutions similar diamagnetic complexes TaCl3(bipyridyl) and TaCl3(o-phenanthroline), and the paramagnetic tris (dibenzoylmethanato) tantalum(III) were prepared. These are the first compounds of tantalum (III) to be characterised.
D. G. Blight, R. L. Deutscher and D. L. Kepert, J. Chem. Soc., Dalton Trans., 1972, 87 DOI: 10.1039/DT9720000087
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