Issue 20, 1972

An inverted relationship between stability and rate of formation of Meisenheimer-type adducts from dinitrothiophen and trinitrobenzene derivatives

Abstract

A σ-adduct (II) is formed by the action of the methoxide ion on 2,4-dinitrothiophen; the equilibrium and rate constants for this process have been determined at 25° in methanol and the striking differences between the dinitrothiophen and the trinitrobenzene systems are discussed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1143-1144

An inverted relationship between stability and rate of formation of Meisenheimer-type adducts from dinitrothiophen and trinitrobenzene derivatives

G. Doddi, G. Illuminati and F. Stegel, J. Chem. Soc., Chem. Commun., 1972, 1143 DOI: 10.1039/C39720001143

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