The observed barrier height to torsion about the N–C(O) bond in NN-dimethylacetamide is found to be dependent on the presence of lithium ions, these ions serving to increase the barrier.
W. Egan, T. E. Bull and S. Forsén, J. Chem. Soc., Chem. Commun., 1972, 1099 DOI: 10.1039/C39720001099
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