Issue 18, 1972

A tridentate unsaturated tertiary phosphine obtained by dehydrogenation of 2,2′-bis(diphenylphosphino)bibenzyl in the presence of rhodium complexes; X-ray crystal structure of the chelate olefin complex RhCl(o-Ph2P·C6H4·CH:CH·C6H4·PPh2-o),CH2Cl2

Abstract

The chelate olefin complex RhCl(o-Ph2P·C6H4·CH:CH·C6H4·PPh2-o) is formed by dehydrogenation of 2,2′-bis(diphenylphosphino)bibenzyl, o-Ph2P·C6H4·CH2·CH2·C6H4·PPh2-o, in the presence of RhI or RhIII compounds, and is shown to be essentially square planar by X-ray structural analysis; four- and five-co-ordinate iridium(I) complexes are also formed by the tridenate olefinic ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1011-1012

A tridentate unsaturated tertiary phosphine obtained by dehydrogenation of 2,2′-bis(diphenylphosphino)bibenzyl in the presence of rhodium complexes; X-ray crystal structure of the chelate olefin complex RhCl(o-Ph2P·C6H4·CH:CH·C6H4·PPh2-o),CH2Cl2

M. A. Bennett, P. W. Clark, G. B. Robertson and P. O. Whimp, J. Chem. Soc., Chem. Commun., 1972, 1011 DOI: 10.1039/C39720001011

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements