The preparations in good yields of the borohydride (π-C5H5)2NbBH4 and of the hydrides (π-C5H5)2NbH(PR3), R3= Ph3 or PhMe2, are described; the latter hydrides are basic and may be protonated giving the dihydride cations [(π-C5H5)2NbH2(PR3)]+.
C. R. Lucas and M. L. H. Green, J. Chem. Soc., Chem. Commun., 1972, 1005 DOI: 10.1039/C39720001005
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