[π-C5H5Fe(CO)2]2SO2 has been prepared from π-C5H5Fe(CO)2Na and SO2 and its molecular stereochemistry determined from a single-crystal X-ray diffraction study; this complex represents the first known molecule in which SO2 alone bridges two transition metal atoms.
M. R. Churchill, B. G. DeBoer, K. L. Kalra, P. Reich-Rohrwig and A. Wojcicki, J. Chem. Soc., Chem. Commun., 1972, 981 DOI: 10.1039/C39720000981
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