The molecular structure of a molybdenum dithiocarbamate showed that its formation proceeds via an oxidative carbon–sulphur bond cleavage followed by formation of a molybdenum–carbene bond.
L. Ricard, J. Estienne and R. Weiss, J. Chem. Soc., Chem. Commun., 1972, 906 DOI: 10.1039/C39720000906
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