Issue 15, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation, identification, and crystal structure of a novel hexanuclear iridium–copper cluster complex

O. M. Abu Salah,   M. I. Bruce,   Melvyn R. Churchill  and  Susan A. Bezman  

Abstract

Cu4Ir2(PPh3)2(C[triple bond, length half m-dash]CPh)8 has been synthesized from IrCl(CO)(PPh3)2 and [Cu(C[triple bond, length half m-dash]CPh)]n and its molecular structure determined via X-ray diffraction; the six metal atoms define an octahedron in which two PPh3Ir moieties are mutually trans, four (C[triple bond, length half m-dash]CPh) units are σ-bonded to each Ir atom, and two (C[triple bond, length half m-dash]CPh) units (one from each Ir) from π-linkages to each of the four equatorial copper atoms.

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Article information

DOI
https://doi.org/10.1039/C39720000858
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 858-859

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Preparation, identification, and crystal structure of a novel hexanuclear iridium–copper cluster complex

O. M. A. Salah, M. I. Bruce, M. R. Churchill and S. A. Bezman, J. Chem. Soc., Chem. Commun., 1972, 858 DOI: 10.1039/C39720000858

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