Thiocarboxamido complexes of manganese and molybdenum
Abstract
Reaction of CpMo(CO)3– and ClCSNMe2 yields CpMo(CO)2CSNMe2 which gives [CpMo(CO)2C(SMe)NMe2]+(isolated eventually as the PF6– salt) with [Me3O]BF4; the same reactions are reported with Mn(CO)4PPh3–; the structures of these complexes are believed to involve the C–S group as a bidentate three electron donor.