Tris(biacetylbismethylimine)iron(II), in acid aqueous media, undergoes a free-radical chain autoxidation process, promoted by iron(III) and inhibited by iron(II), in which ligands are oxidized without breaking the metal–ligand bond or oxidation of the iron(II).
H. L. Chum, A. M. G. da Costa and P. Krumholz, J. Chem. Soc., Chem. Commun., 1972, 772 DOI: 10.1039/C39720000772
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