The sequence of trimethylsilanol elimination in the mass spectra of trimethylsilyl steroidal ethers has been studied with the aid of 18O-labelling, and found to be dependent on the structural environment of the trimethylsilyloxy-functions.
P. Vouros and D. J. Harvey, J. Chem. Soc., Chem. Commun., 1972, 765 DOI: 10.1039/C39720000765
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