Alstonisidine, a bisindole alkaloid from Alstonia muelleriana, is assigned the revised structure (II) on the basis of its biomimetic synthesis from quebrachidine (III) and macroline (IV).
D. E. Burke, J. M. Cook and P. W. Le Quesne, J. Chem. Soc., Chem. Commun., 1972, 697 DOI: 10.1039/C39720000697
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