Issue 11, 1972

Thermal and photochemical rearrangements, and X-ray crystal structure of a 2-benzazocine derivative

Abstract

Dimethyl 8-oxo-1-phenyl-12-azatricyclo[7,2,1,02,7]dodeca-2(9),3,5,11-tetraene-10,11-dicarboxylate (4) at 115° in toluene undergoes a novel rearrangement to a benzazocine derivative (5) which undergoes further rearrangement on photolysis; the structure of (5) has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 680-681

Thermal and photochemical rearrangements, and X-ray crystal structure of a 2-benzazocine derivative

A. Padwa, P. Sackman, E. Shefter and E. Vega, J. Chem. Soc., Chem. Commun., 1972, 680 DOI: 10.1039/C39720000680

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements