Nanosecond flash photolysis, quenching, and phosphorescence studies show that the photoreactions of thiobenzoate O-esters proceed mainly via the lowest nπ* triplet state; chemical evidence for the formation of a 1,4-diradical intermediate is presented.
D. H. R. Barton, M. Bolton, P. D. Magnus, P. J. West, G. Porter and J. Wirz, J. Chem. Soc., Chem. Commun., 1972, 632 DOI: 10.1039/C39720000632
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