The 19F n.m.r. spectra of solutions in SbF5 and the Raman spectra of the solids show that the compounds XeOF4·2SbF5 and XeO2F2·2SbF5 have the ionic structures XeOF3+·Sb2F11– and XeO2F+·Sb2F11–, that the XeOF3+ ion has the expected trigonal bipyramidal AX4E type structure and that the XeO2F+ ion has a pyramidal structure analogous to the isoelectronic XeO3.
R. J. Gillespie, B. Landa and G. J. Schrobilgen, J. Chem. Soc., Chem. Commun., 1972, 607 DOI: 10.1039/C39720000607
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