2-Lithio-2-trimethylsilyl-1,3-dithian reacts with carbonyl compounds R1R2CO to give alkylidenedithians, potentially valuable synthetic intermediates for formation of R1R2CHCO2H, R1R2CHCHO, and R1R2R3CCHO.
P. F. Jones and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1972, 526 DOI: 10.1039/C39720000526
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