Issue 8, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Oxidation of alcohol to co-ordinated carboxylate with a dioxygen complex of ruthenium. Examples of reversible hydrogen transfer to an isocyanide ligand

D. F. Christian,   G. R. Clark,   W. R. Roper,   J. M. Waters  and  K. R. Whittle  

Abstract

The dioxygen complex, Ru(O2)(CO)(CNR)(PPh3)2(R =p-tolyl), reacts with alcohols, R′CH2OH (R′= Me, Et, or Ph) forming Ru(O2CR′)(CHNR)(CO)(PPh3)2; when the bidentate carboxylate group is replaced by iodide the ruthenium hydride RuHI(CO)(CNR)(PPh3)2 results which reacts with acetate with returns of hydride to the isocyanide ligand forming Ru(O2CMe)(CHNR)(CO)(PPh3)2.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39720000458
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 458-459

Permissions

Request permissions

Oxidation of alcohol to co-ordinated carboxylate with a dioxygen complex of ruthenium. Examples of reversible hydrogen transfer to an isocyanide ligand

D. F. Christian, G. R. Clark, W. R. Roper, J. M. Waters and K. R. Whittle, J. Chem. Soc., Chem. Commun., 1972, 458 DOI: 10.1039/C39720000458

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements