Cyanation and nitration of cobalt(II) tetradehydrocorrin salts yield cobalt(III) derivatives which can be converted readily into crystalline neutral cobalt(I) complexes; these substituted cobalt(I) tetradehydrocorrins are reversibly oxidised to stable cobalt(II) complex at potentials anodic to the oxidation potential of the unsubstituted cobalt(I) complex.
C. M. Elson, A. Hamilton, A. W. Johnson and C. Stubbs, J. Chem. Soc., Chem. Commun., 1972, 453 DOI: 10.1039/C39720000453
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