The photo-induced isomerization of an aryl isocyanide in methanol into a cyanide received assistance from a strong electron donating substituent in the para-position; in aprotic solvents the rearrangement was inhibited.
V. T. Ramakrishnan and J. H. Boyer, J. Chem. Soc., Chem. Commun., 1972, 429 DOI: 10.1039/C39720000429
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