Issue 7, 1972

Reactions of carbene with 1,1-dicyclopropylethylene. A new tool to investigate radical cycloadditions

Abstract

Fluorenylidene reacts with 1,1-dicyclopropylethylene to give a cycloadduct (5) and the rearranged adduct (6) in a ratio of 10:1; dilution with decalin inverses the ratio to 1:3, which may be due to the increased amount of triplet fluorenylidene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 389-390

Reactions of carbene with 1,1-dicyclopropylethylene. A new tool to investigate radical cycloadditions

N. Shimizu and S. Nishida, J. Chem. Soc., Chem. Commun., 1972, 389 DOI: 10.1039/C39720000389

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