Treatment of adamantan-2-ol in carbon tetrachloride or benzene with mercuric oxide and iodine, followed by irradiation at 70° with a tungsten lamp, afforded oxa-adamantane (ca. 50%); the course of the reaction, which involves the loss of one carbon atom as carbon monoxide, is discussed.
R. M. Black, G. B. Gill and D. Hands, J. Chem. Soc., Chem. Commun., 1972, 311 DOI: 10.1039/C39720000311
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