Issue 5, 1972

An unprecedented nucleophilic displacement by bicarbonate anion, and its implications in the oxidation of alkyl toluene-p-sulphonates with dimethyl sulphoxide-sodium bicarbonate

Abstract

Bicarbonate anion is shown to be a more effective nucleophile than Me2SO when treated with the toluene-p-sulphonate (I); the elements of carbon dioxide are retained in the product as the cyclic carbonate (II).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 257-258

An unprecedented nucleophilic displacement by bicarbonate anion, and its implications in the oxidation of alkyl toluene-p-sulphonates with dimethyl sulphoxide-sodium bicarbonate

N. Bosworth and P. D. Magnus, J. Chem. Soc., Chem. Commun., 1972, 257 DOI: 10.1039/C39720000257

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