The decrease in the barrier to pyramidal inversion at phosphorus which is observed when a trimethylsily ligand is replaced by a trimethoxysilyl ligand is ascribed to negative hyperconjugation.
R. D. Baechler and K. Mislow, J. Chem. Soc., Chem. Commun., 1972, 185 DOI: 10.1039/C39720000185
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