Treatment of bilirubin IX-α in dimethyl sulphoxide with acetic acid at 85° or with concentrated hydrochloric acid at room temperature causes isomerisation and formation of bilirubin III-α and bilirubin XIII-α whereas similar treatment at room temperature with sodium hydroxide or sodium methoxide does not.
A. F. McDonagh and F. Assisi, J. Chem. Soc., Chem. Commun., 1972, 117 DOI: 10.1039/C39720000117
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