The reaction of CS2 with [PtF(PPh3)3][HF2] gives a bisphosphine platinum dithiofluoroformate complex [Pt(S2CF)(PPh3)2][HF2], the result of insertion of CS2 into the Pt–F bond.
J. A. Evans, M. J. Hacker, R. D. W. Kemmitt, D. R. Russell and J. Stocks, J. Chem. Soc., Chem. Commun., 1972, 72 DOI: 10.1039/C39720000072
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