Methyl methacrylate, a cyclic olefin, and two alk-1-enes are efficiently converted into their corresponding epoxides by m-chloroperbenzoic acid at elevated temperatures in the presence of a small amount of a radical inhibitor, which prevents thermal decomposition of the peracid.
Y. Kishi, M. Aratani, H. Tanino, T. Fukuyama, T. Goto, S. Inoue, S. Sugiura and H. Kakoi, J. Chem. Soc., Chem. Commun., 1972, 64 DOI: 10.1039/C39720000064
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