The complex formed by cobalt(II) chloride with the macrocyclic ligand dodeca(dimethylamino)cyclohexaphosphazene is ionic, the metal in the cation having a strongly distorted trigonal bipyramidal configuration, in which the axial bonds are significantly longer than the equatorial bonds; the anion is the previously unrecognised hexachlorodicobaltate(II) ion.
W. Harrison, N. L. Paddock, J. Trotter and J. N. Wingfield, J. Chem. Soc., Chem. Commun., 1972, 23 DOI: 10.1039/C39720000023
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